Stereo-Chemical Investigation of 2-Amino-4-(P-Chloro-Phenyl)-Thiazole Complexes With Bivalent Mn, Co, Ni, Cu and Zn Acetyl Acetonates

L.M. Sharma, R. C. Saxena, M. C. Sharma and Mahesh Srivastava

¹Department of Chemistry, N.A.S. College, Meernt-250 001 India.

²Department of Chemistry, L.R. (P.G.) College, Sahibabad-201 005 (Ghaziabad) India.

ABSTRACT:

A new bidentate ligand 2~amino-4-p-Chloro-phenyl)-Thiazole and its complexes of general formula; M (ACPT) (AA)2 where M=Mn (II), Co (II), Ni (II), Cu (Il) and Zn (II), ACPT=2-amino-4-(p-chIoro-phenyl) thiazole and AA=Acetyl acetonate (C5H7O2)-group, have been prepared and isolated. Newly synthesized complexes were characterized by elemental analysis, Conductance measurement, magnetic moment, I. R. and electronic spectral studies. All the complexes are found as monomeric and a distorted octahedrel geometry is assigned to all of them.

KEYWORDS:

Stereo-Chemical; Complexes; Bivalent

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Copy the following to cite this article: Sharma L. M, Saxena R. C, Sharma M. C, Srivastava M. Stereo-Chemical Investigation of 2-Amino-4-(P-Chloro-Phenyl)-Thiazole Complexes With Bivalent Mn, Co, Ni, Cu and Zn Acetyl Acetonates. Orient J Chem 1992;8(3).

Copy the following to cite this URL: Sharma L. M, Saxena R. C, Sharma M. C, Srivastava M. Stereo-Chemical Investigation of 2-Amino-4-(P-Chloro-Phenyl)-Thiazole Complexes With Bivalent Mn, Co, Ni, Cu and Zn Acetyl Acetonates. Orient J Chem 1992;8(3). Available from: http://www.orientjchem.org/?p=39141