Synthesis and Structure of Hg, Sb and Rh Metal Complexes of N-Alkylimines

Salim S. Al-Showiman

Department of Chemistry, College of Science, King Saud University, Riyadh-11451 Saudi Arabia.

ABSTRACT:

Different N-alkylimines have been synthesized and were reacted with HgCI2, SbCI3 and RhCl3. (H2O)3. The corresponding complexes of the general formulae HgCl2L2 SbCl3L2MeOH and RhCI3L3 were obtained. Spectroscopic evidence by IR, 1H NMR, 13C NMR, 199Hg NMR, Mass spectroscopy as well as elemental analysis pointed out the existence of a weak dative bond between these imines and the metals. These complexes were found to be neutral as indicated by their electric conductance.

KEYWORDS:

Structur;Complexes; N-Alkylimines

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Copy the following to cite this article: Al-Showiman S. S. Synthesis and Structure of Hg, Sb and Rh Metal Complexes of N-Alkylimines. Orient J Chem 1989;5(1).

Copy the following to cite this URL: Al-Showiman S. S. Synthesis and Structure of Hg, Sb and Rh Metal Complexes of N-Alkylimines. Orient J Chem 1989;5(1). Available from: http://www.orientjchem.org/?p=41279