Synthesis and Spectral Characterization of Mixed-Ligand Phosphine Complexes of Rhodium (1) With 1-Phenyl Tetrazoline-5-Thione

R. N. Pandey^*, D. P. Singh, Priya and Rajnish Kr. Singh    

P. G. Centre of Chemistry (M.U.), College of Commerce, Patna - 800 020 India.

ABSTRACT:

The reaction between 1-phenyltetrazoline-5-thione and [RhX(Pf)3] (X = Cl–, Br–, I–, NCS–, SnCl) in benzene as well as in monoethyl ether of ethyleneglycol were carried out. All the isolated solid products have been assigned Trans-square planer configuration, having general formula [RhX(Pf)3 (ligand)2] using various physico- chemical data.

KEYWORDS:

Rh (1) organometallics; spectral characterization

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Copy the following to cite this article: Pandey R. N, Singh D. P, Priya P, Singh R. K. Synthesis and Spectral Characterization of Mixed-Ligand Phosphine Complexes of Rhodium (1) With 1-Phenyl Tetrazoline-5-Thione. Orient J Chem 2010;26(4).

Copy the following to cite this URL: Pandey R. N, Singh D. P, Priya P, Singh R. K. Synthesis and Spectral Characterization of Mixed-Ligand Phosphine Complexes of Rhodium (1) With 1-Phenyl Tetrazoline-5-Thione. Orient J Chem 2010;26(4). Available from: http://www.orientjchem.org/?p=24424