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The Ph Metric Studies of Complexes of 4-Amino-3-Naphthol-Sulphonic Acid and 6-Amino-5-Naphthol- Sulphonic Acid with Transition Metal Ions

S. D. Deosarkar1* and M. L. Narwade2

1Department of Chemistry, S. F. S. College, Seminary Hills, Nagpur - 440 010 India. 2Vidyabharti Mahavidyalay, Amravati - 444 602 India.

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ABSTRACT:

The interaction of Co (II), Cu (II) and Ni (II) metal ions with 4-Amino-3-Naphthol-Sulphonic Acid (4A-3N-SA) and 6-Amino-5-Naphthol-Sulphonic Acid (6A-5N-SA) has been investigated pH metrically. It showed the formation of 1:1 and 1:2 complexes. The values of pK (proton-ligand stability constant) and logK (metal-ligand stability constant) at 0.1M ionic strength and 28 °C ± 0.1° were calculated.

KEYWORDS:

ph; metric studies; transition metal ions

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Deosarkar S. D, Narwade M. L. The Ph Metric Studies of Complexes of 4-Amino-3-Naphthol-Sulphonic Acid and 6-Amino-5-Naphthol- Sulphonic Acid with Transition Metal Ions. Orient J Chem 2008;24(1).


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Deosarkar S. D, Narwade M. L. The Ph Metric Studies of Complexes of 4-Amino-3-Naphthol-Sulphonic Acid and 6-Amino-5-Naphthol- Sulphonic Acid with Transition Metal Ions. Orient J Chem 2008;24(1). Available from: http://www.orientjchem.org/?p=23309



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