Synthesis and Characterization of Cu(Ii), Co(Ii), Ni(Ii) Complexes with Schiff Bases Derived from 3-(4-Chlorophenoxymethyl)-4-Amino-5-Mercapto-1,2,4-Triazole

Vidyavati Reddy¹, Nirdosh Patil², Tukaram Reddy¹ and S. D. Angadi^1*

¹Department of studies and research in Chemistry, Gulbarga University, Gulbarga - 585 106 India. ²Appa Institute of Engineering and Technology, Gulbarga - 585106 India.

ABSTRACT:

A new bidentate Schiff base ligands derived from 3-(4-chlorophenoxymethyl)-4-amino-5-mercapto-1,2,4-triazole with substituted salicylaldehyde and its Cu(II), Co(II) and Ni(II) complexes have been synthesized and characterized by elemental analysis, IR, electronic, 1HNMR and ESR spectra. The analytical data and spectral data reveals that the composition of the complexes to be ML2(H2O)2 where M = Cu(II), Co(II), Ni(II) and are non-electrolytic in nature. It is found that these complexes exhibit octahedral geometry. The various spectral data shows the monobasic bidentate character of the ligand coordinating through.

KEYWORDS:

Triazoles; Metal complexes; Spectral and Magnetic susceptibility

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Copy the following to cite this article: Reddy V, Patil N, Reddy T, Angadi S. D. Synthesis and Characterization of Cu(Ii), Co(Ii), Ni(Ii) Complexes with Schiff Bases Derived from 3-(4-Chlorophenoxymethyl)-4-Amino-5-Mercapto-1,2,4-Triazole. Orient J Chem 2008;24(1).

Copy the following to cite this URL: Reddy V, Patil N, Reddy T, Angadi S. D. Synthesis and Characterization of Cu(Ii), Co(Ii), Ni(Ii) Complexes with Schiff Bases Derived from 3-(4-Chlorophenoxymethyl)-4-Amino-5-Mercapto-1,2,4-Triazole. Orient J Chem 2008;24(1). Available from: http://www.orientjchem.org/?p=23200