Synthesis and Characterization of Cu(II) Complex of Bis (Thiotrithiazyl) Thioureate
Anjul Singh1 and S. P. S. Jadon2*
1Department of Chemistry, D.S. College, Aligarh - 202 001 (India) 2Department of Chemistry, S.V. College, Aligrah - 202 001 (India)
Cu (II) acetate reacts with the ligands, Bis (thiotrithiazyl) thioureate, derived from thiotrithiazyl chloride with thiourea. The authenticity of the complex has been established by elemental analysis Mass, IR, electronic, ESR, NMR and X-ray spectral studies. The ligand acts as pentadentate with sulfur and nitrogen atoms of thioamide and thiotrithiazyl ring, acting as donor sites. It is proposed that Cu(II) complex is distorted orthorhombic and paramagnetic in nature.
KEYWORDS:S4N3Cl; Bis (thiotrithiazyl) thioureate; Cu(II) complex
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Copy the following to cite this URL: Singh A, Jadon S. P. S. Synthesis and Characterization of Cu(II) Complex of Bis (Thiotrithiazyl) Thioureate. Orient J Chem 2007;23(2). Available from: http://www.orientjchem.org/?p=20098 |
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