Studies on the Complexes of Oxovanadium (IV) and Titanium(III) Containing Phthalimide and Aminophenols

M. A. J. Mia, M. S. Islam, S. C. Pal and T. K. Barma

Department of Chemistry, Rajshahi University, Rajshahi 6205 Bangladesh.

ABSTRACT:

A few novel mixed ligand complexes of VO(l V) and Ti(lll) containing phthalimide as primary and 2- aminophenol and 3 - aminophenol as secondary ligands have been synthesised. They have been fomulated on the basis of elemental analysis and conductivity data and their structures confirmed by magnetic measurements and infraed and electonic spectral studies. The complexes have the general composition: K[M (L)2 (L')2] where M=VO(l V) andTi (IIl), L=anion of phthalimide L' = anion of 2 - aminophenol and 3 - aminophenol. Mola conductance values reveal that the oxovanadium complexes and the Ti (III) complex with 2 - aminophenol are 1:1 electrolyte in nature. Magnetic measurements and infrared and electronic spectral data speak in favour of the octahedral stereochemistry for the complexes.

KEYWORDS:

Containing; Phthalimide; Aminophenols;

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Copy the following to cite this article: Mia M. A. J, Islam M. S, Pal S. C, Barma T. K. Studies on the Complexes of Oxovanadium (IV) and Titanium(III) Containing Phthalimide and Aminophenols. Orient J Chem 1994;10(3).

Copy the following to cite this URL: Mia M. A. J, Islam M. S, Pal S. C, Barma T. K. Studies on the Complexes of Oxovanadium (IV) and Titanium(III) Containing Phthalimide and Aminophenols. Orient J Chem 1994;10(3). Available from:http://www.orientjchem.org/?p=38267