ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Determination of Caffeic Acid in Cigarette Smoke and Urine by Electrochemical Methods Using Supramolecular Electroactive Materials grafted in Screen Printed Carbon Electrode

Syed Kashif Ali1*, Geetu Gambhir2, Gulrana Khuwaja3, Sayeed Shabi4, Safaa F. Saleh4,5, Angum M. M. Ibrahim5 Amal. A. Noureideen6 Mawada Abubaker Abdelgadir Mohammed7 and Sumathi Nagarajan4

DOI : http://dx.doi.org/10.13005/ojc/390606


Abstract:

Selective determination of caffeic acid, was carried out by using Screen Printed Carbon Electrode (SPCE) to give a reliable, scalable, and inexpensive electrochemical method with enhanced analytical performance. SPCE was first activated by linear sweep voltammetry using KOH solution, followed by its electrochemical grafting with cyclodextrins. Britton Robinson buffer (BRB) solution having pH 8.1, demonstrated a clear electrocatalytic impact towards caffeic acid oxidation, which indicated a greater current response compared to the activated electrode in the cyclic voltammetric and square wave voltammetric (SWV) investigations. The SWV waves at the activated SPCE was used under ideal conditions to produce a linear calibration curve with detection limits of (LoD, 4 sb/m) and quantification limits of (LoQ, 11 sb/m) of 0.38 M and 1.1 M, respectively.

Keywords:

Cigarette Smoke; Determination of Caffeic acid; Electrochemical methods; Materials

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