Abstract

V. V. Kadam^1*, A. B. Nikumbh², T. B. Pawar³ and V. A. Adole⁴

DOI : http://dx.doi.org/10.13005/ojc/370510

The densities and viscosities of electrolytes are essential to understand many physicochemical processes that are taking place in the solution. In the present research, the densities and viscosities of lithium halides, LiX (X = Cl, Br, I ) and KCl in (0, 20, 40, 50, 60, 80 and 100) mass % of methanol + water at 313.15K were calculated employing experimental densities (ρ), the apparent molar volumes( ϕv) and limiting apparent molar volumes (0v) of the electrolytes. The (0v) of electrolyte offer insights into solute-solution interactions. In terms of the Jones-Dole equation for strong electrolyte solution, the experimental data of viscosity were explored. Viscosity coefficients A and B have been interpreted and discussed. The B-coefficient values in these systems increase with increase of methanol in the solvents mixtures. This implied that when the dielectric constant of the solvent decreases, so do the solvent-solvent interactions in these systems.

Apparent Molar Volume; Density; Viscosity

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