ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Synthesis and Spectral studies of Ru (II) complexes with Macrocyclic Ligands

Ashish Rajak1, Arpit Srivastava1, Ramakant1, Subhash Chandra Shrivastava1*, Ranjeet Singh Chauhan2, Uday Singh Patel3 and Shekhar Srivastava1

DOI : http://dx.doi.org/10.13005/ojc/370401


Abstract:

Fifteen Ru (II) complexes of the type [RuCl2(L)] (where L= N4 donor macrocyclic ligands) have been synthesised by reaction of [(RuCl2(DMSO)4] with fifteen macrocyclic Schiff base ligands containing N4 donors groups. The prepared fifteen [RuCl2(L)] complexes were characterised by elemental analysis, molar conductivity, UV-visible, IR, X- ray photoelectron spectra (XPS) and magnetic susceptibility measurementsand an octahedral geometry was proposed for all these complexes.

Keywords:

Magnetic Susceptibility Measurement; N4 Macrocyclic Shiff Base Complexes; Ru (II) Complexes, Elemental Analysis; UV-visible

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