Abstract
Studies of Some Novel Chromium Pyridine Dicarboxylate Complexes
Chauhan Jayprakash S1, Patel Rameshchandra P1. and Pandya Ajit V2
DOI : http://dx.doi.org/10.13005/ojc/300435
Abstract:
Chromium pyridine di-carboxylate complexes are synthesized from Chromium (III) with pyridine 2, 6- dicarboxylic acid, pyridine 2, 3 and 2, 5- dicarboxylic acids. Chromium forms colored complexes. Chromium (III) forms a violate complex with pyridine 2, 6- dicarboxylic acid and purple violate complex with pyridine 2, 3 and 2, 5- dicarboxylic acids. The job’s method indicates metal ligand ratio to be 1:2. The interpretation of UV-VIS spectra indicates octahedral geometry and IR spectra give clue about the presence of Metal – Nitrogen and Metal- Oxygen bond. We have also made an effort to compare the spectrum of all the three complexes.
Keywords:Chromium (III) Complex; pyridine dicarboxylic acids; Job;s method; spectra
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