Abstract

Vikas Mangla¹ and Gursharan Singh*²

DOI : http://dx.doi.org/10.13005/ojc/350324

MoOCl₄ reacts with 1-methylimidazole, 4-methylpiperidine and trimethylsilylimidazole (equimolar molar amounts) in solvent CH₃CN to provide MoO₂Cl₄(C₃H₃N₂CH₃) [1], MoOCl₄(C₅H₉NHCH₃)CH₃CN [4] and MoO₂Cl₂(C₃H₄N₂), [7]. MoOCl₄ reacts with twice the moles of 1,4-diaminobutane, 2-methylpyridine, 4-methylpiperidine and 1-methylpyrrolidine in solvent CH₃CN to provide: MoOCl₄(H₂NC₄H₈NH₂)₂ [2], MoOCl₄(C₅H₄NCH₃), [3], MoOCl₄(C₅H₉NHCH₃)₂, [5], MoOCl₄(C₅H₉NHCH₃)₂, [6] and MoO₂Cl₄(C₄H₈NCH₃)₂, [8]. Complexes have been studied by techniques: elemental quantitative analysis, FTIR, ¹H NMR, Mass (LC-MS).

1,4-Diaminobutane; MoOCl4; 1-Methylimidazole; 4-Methylpiperidine; 1-Methylpyridine; 1-Methylpyrrolidine; Trimethylsilylimidazole

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