Abstract

Ali A. A. Al-Riyahee, Hanaa H. Hadadd and Baydaa H. Jaaz

DOI : http://dx.doi.org/10.13005/ojc/340632

A novel set of Cobalt(II), Copper(II) and Nickel(II) complexes of  ligands, (E)-2-(((2,5-difluorophenyl)imino) methyl)phenol (A), (E)-2,4-dibromo-1-((2-hydroxybenzylidene) amino)anthracene-9,10-dione (D) & (Z)-1-((1-([1,1'-biphenyl]-4-yl)-2-bromoethylidene) amino)-2,4-dibromo anthracene-9,10-dione (E) were synthesized and characterized. Their structures were investigated on the basis of CHN, conductance measurements and spectral studies (H¹-NMR & C¹³-NMR,FT-infrared and Electronic spectroscopies), cyclic voltammetry. It has observed from spectral and analytical studies that metal complexes have the composition of (ML₂.X₂) and one mole of ligand behaves as bidentate chelating agents around the corresponding metal ion. From solubility test, we obtained that metal complexes of ligands A, D and E had no ionic properties and dissolve partially in polar and slightly in nonpolar solvents. These results confirmed the behavior of metal complexes as weak electrolyte from their low value of molar conductivity. Conductance data and solubility test of the complexes enhanced them to be (1:2 M:L ratio). All data confirmed an octahedral geometry of these complexes and their structures as {[M (A, D or E)₂(CH₃COO)₂], when M= Co or Ni} and {[Cu (A, D or E)₂ Cl₂]}. Cyclic voltammetry measurements were accomplished of Cobalt(II), Copper(II) and Nickel(II) complexes using Pt wire as counter electrode and Ag/AgNO₃ as reference electrode and (Bu₄N⁺PF₆⁺) as supporting electrolyte. The result exhibit the irreversible process showing single one electron transfer process of Cobalt(II) and Nickel(II) complexes and unique quasi-reversible redox couple is attributed to Cu(II) complexes.

Cobalt; Copper; Cyclic Voltammetry; Metal Nomplexes; Nickel; Schiff Bases

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