ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Thermodynamics op the Binding of Guest Molecules to α -Cyclodextrin: an Isoequilibrium Relationship

Liang Feng Han1* and Wolfgang Linert2


Abstract:

It is shown that acetonitrile, n-butanol, 2-butanone, i-propanol, n-propanol and methylorange form defined 1:1 inclusion complexes with a-cyclodextrin in aqueous acidic medium. The dissociation constants of these complexes have been determined for various temperatures by spectroscopic means analyzed with a Marquardt non-liner regression method, Isoequilibrium relationships are found and discussed on the basis of recent theoritical descriptions.

Keywords:

Binding; Isoequilibrium; Relationship

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