Abstract

Gulrez Nizami, Poonam Garg and Shamim Ahmad

The Schiff base 5-methyl 2- hydroxy acetophenone morpholine N- thiohydrazone has reacted with Ti (III), V(III), oxovanadium (IV),Mn (II), Mn (III), and Fe (III) to form co-ordination compounds having general formula [M(C14H19O2N3S).3H2O]+Cl- where M=Ti,V, Fe Mn etc. These adducts have been characterized on the basis of elemental analyses, molar conductance, infrared and visible spectra, magnetic susceptibility measuements and TGA. The ligand behaves in dibasic tridentate manner. All these compounds are paramagnetic in character and have octahedral geometry.

Co-ordination compounds; octahedral geometry and Paramagnetism

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