ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Reactions of 2-Thioxoper Hydro-1, 3-Thiazin-4 Ones with Oxovanadium (Iv), Chromium (Iii), Manganese (Ii), Iron (Ii) And Iron (Iii)

B. P. Singh, K. K. Singh1 and J.P. Singh2


Abstract:

In this paper, the reaction of 2-thioxoperhydro – 1, 3 – thiazin – 4 ones; with VO(IV), Cr(III), Mn(II), Fe(II) and Fe(III) ions lead to the formation of M(TP)­X (H2O)Y[M=Mn(II), Cr(III), Fe(III); x=1 or 2; y=2 or 3], VO(TP)2 and [Fe(TPH)Cl2(PPh3)2]. These complexes have been characterized by analytical, magnetic, thermogravimetric and spectral (IR, UV and Visible) studies and their tentative structures are proposed.

Keywords:

Spectroscopic methods; Metal complexes; Fungicides; Pesticides

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