Abstract

A.V. Shakhvorostov¹, Z. B. Atabekova^1*, B. S. Selenova¹, G. Zh. Yeligbayeva¹ and G. I. Dzhardimalieva²

DOI : http://dx.doi.org/10.13005/ojc/320517

The paper presents the results of synthesis of polyporphyrin structures and metal complex catalyzers at their basis. Porphyrin to be derived from the addition reaction of pyrrole and formaldehyde. Metal complex catalyzers to be derived at the reaction of complex formation of ions of Mn²⁺, Co²⁺, Ni²⁺ and Fe³⁺ with porphyrin. The structure, physical and chemical properties of derived materials to be examined with IR spectroscopy, differential thermal analysis, thermogravimetric analysis, scanning electron microscopy investigation. Catalytic activity of synthesized catalytic systems to be established at the reaction of decompounding of hydrogen peroxide and alkylaromatics oxidation by hydrogen peroxide. The processes have been conducted under soft conditions, and also at different organic solvents.

Porphyrin; metal complex catalyzers; hydrogen peroxide; oxidation; alkylaromatics

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