Abstract

Mohammed A. Al-Anber

DOI : http://dx.doi.org/10.13005/ojc/290420

A mononuclear complex of [Zn(tta)₂(H₂O)₂] (3) (tta = deprotonated of 1-thenoyl-4,4,4-trifluoro­acetone (1)) has been prepared by the reaction of 1-thenoyl-4,4,4-trifluoro­acetone (H-tta: 1) with Zn(OAc)₂.4H₂O (OAc = O₂CMe) in a 2:1 molar ratio. Complex 3 can be extended to form a coordination polymers of general formula [Zn(tta)₂(X)]_n (X =  4,4'-bipy (4), pz (5)) by the reaction of zinc atom in 3 with s-donor ligand such as 4,4-bipyridine (4,4'-bipy) and pyrazin (pz). The reaction completion was controlled via FTIR and elemental analysis.

Zinc; 4,4’-Bipyridine; Pyrazine; Polymers; 1-thenoyl-4,4,4-trifluoro¬acetone;

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