ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Kinetic and Thermodynamic study for the Oxidation of 4-Oxo-4-phenyl  butanoic Acid by Tripropylammonium fluorochromate  in Aqueous Acetic Acid Medium

A. Yogananth1 and S. Sheik Mansoor2*

DOI : http://dx.doi.org/10.13005/ojc/310102


Abstract:

Tripropylammonium fluorochromate (TriPAFC) in acetic acid-water medium oxidizes 4-oxo-4-phenyl butanoic acid (4-Oxo acid) in the presence of perchloric acid.  The reaction is first order each in [TriPAFC], [4-Oxo acid] and [H+]. From the observed kinetic results a suitable mechanism has been proposed.

Keywords:

4-Oxo acid; kinetics; oxidation; tripropylammonium fluorochromate

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