Abstract

S. Mohan, S, Gunasekaran* and K. G. Ravikumar

All the general quadratic valence force field potential constants of PCI4F molecule are evaluated afresh using kinetic constants. Using the present potential constants, the other molecular constants such as vibrational mean amplitudes, coriolis coupling constants and centrifugal distortion constants are calculated. The values of these molecular constants are in the expected range. Further more, it is shown that the kinetic constants method leads to acceptable sets of molecular constants.

Analysis; Phosphorus; Fluoro

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