ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Electron Donor Acceptor Interactions of N,N' - Dimethylanilines With Chloranil

A. Ram Reddy* and A. S. N, Murthy


Abstract:

Electron donor-acceptor interactions between N,N'-dimethlanline and chloranil have been investigated in different solvents by electronic absorption spectroscopy. In corbon tetrachloride and More form only charge transfer band is obtained whereas in 1,2-dichloroethane, isopropanol methanol and acetonitrile solvents the interaction led to the reaction product, crystal violet . The kinetics are markedly affected by the solvent polarity. The substitution at para position in dimethylaniline finders the formation of the reaction product.

Keywords:

Electron; Dimethylanilines; Chloranil

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