Abstract

C. Theivarasu¹, S. Mylsamy¹ and N. Sivakumar²

The removal of Malachite Green (MG) by Cocoa (Theobroma cacao) Shell Activated Carbon (CSAC) was investigated in present study. Adsorption studies were performed by batch experiments as a function of process parameters such as initial pH, contact time, initial concentration and adsorbent dose. A comparison of kinetic models applied to the adsorption of MG on CSAC was evaluated for the pseudo-first order and pseudo-second order kinetic models. Results showed that the pseudo-second order kinetic model was found to correlate the experimental data well. The experimental equilibrium adsorption data was represented with Langmuir, Freundlich, Tempkin, Dubinin-Radushkevich and Flory-Huggins isotherms. The experimental data obtained in the present study indicated that activated carbon developed from cocoa shell can be attractive options for dye removal from waste water.

Adsorption; Malachite Green; Cocoa shell; Kinetics; Isotherm

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