Abstract

Jyotsna Pandey

4-Morpholinyl thiocarbonic acid amide synthesized and its Cu(i) complex was prepared. Both were characterized on the basis of elemental analysis, spectral studies, magnetic susceptibility measurement and amperometric titration. Analytical data indicate metal to ligand ratio 1:2. Infrared spectra showed the complexation through the S and N both. Magnetic measurement confirmed the diamagnetic behavior of the complex. An amperometric method for the estimation of Cu(I) with MTA further confirmed the MTA:Cu ratio 1:1. Experimental and calculated statistical data support the utility of the method for determination of Copper.

4-morpholinyl thio carbonic acid amide; copper complex; spectral studies; amperometric titration

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