ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Abstract

Micellar Catalysis of Hydroperoxide Anion Assisted Hydrolysis of Mono-2,4-Dichlorophenyl Phosphate Ester

1Anupam Singh, 1Meera Sharma and 2Pratibha Singh


Abstract:

The micellar catalysed reactions of hydroxide and hydroperoxide anions with mono-2,4-dichlorophenyl phosphate has been investigated. Borate ion accelerate the reaction. The kinetic rate data in [OH-] can be accounted for quantitatively in term of the pseudophase ion exchange model, but this model fits rate data only qualitatively for reaction of [HO2-].

Keywords:

Micellar catalysis; Substituted phosphate ester

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