Abstract

R. S. Verma and R. P. Mathur

The saturated ligand environment produced by various ligands containing nitrogen and oxygen donor atoms in 50% ethanol (V/V) around Nd(III), has been studied with respect to hypersensitive transition (4I9/2 2 4G5/2). The thermodynamics of hypersensitive transition have been studied and correlated with spectral parameters. The thermodynamic parameters include thermodynamic efficiency and partition function of the said transition.

Thermodynamic behaviour; hypersensitive transition; Nd(III)-Doped system

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