Abstract

Eric MUSENGIMANA and Claver FATAKANWA

DOI : http://dx.doi.org/10.13005/ojc/290426

Since the discovery of olefin metathesis reactions, various catalysts have been developed but those based on Ruthenium and N-heterocyclic carbenes (NHC) ligands are particularly more efficient. Herein, we report a synthesis of NHC precursors derived from the Tröger’s base and its analogues which can be used in the synthesis of the new kind of metathesis catalysts. The NHC derived from the Tröger’s base present a particular chirality that could affect stereoselectivity of catalysis, and the form “V” of these ligands implies that the aromatic substituents point totally outside the coordination sphere of the metal, where would be no steric hindrance unlike what happens with the usual NHC.

NHC (N-heterocyclic carbenes);Tröger’s base;perhalogenated adducts;thioureas adducts

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