Electron Donor Acceptor Interactions of N,N' - Dimethylanilines With Chloranil

A. Ram Reddy* and A. S. N, Murthy

Department of Chemistry, Indian Institute of Teehnology, Delhi-110 016 India.

ABSTRACT:

Electron donor-acceptor interactions between N,N'-dimethlanline and chloranil have been investigated in different solvents by electronic absorption spectroscopy. In corbon tetrachloride and More form only charge transfer band is obtained whereas in 1,2-dichloroethane, isopropanol methanol and acetonitrile solvents the interaction led to the reaction product, crystal violet . The kinetics are markedly affected by the solvent polarity. The substitution at para position in dimethylaniline finders the formation of the reaction product.

KEYWORDS:

Electron; Dimethylanilines; Chloranil

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Copy the following to cite this article: Reddy A. R, Murt A. S. N. Electron Donor Acceptor Interactions of N,N' - Dimethylanilines With Chloranil. Orient J Chem 1989;5(2).

Copy the following to cite this URL: Reddy A. R, Murt A. S. N. Electron Donor Acceptor Interactions of N,N' - Dimethylanilines With Chloranil. Orient J Chem 1989;5(2). Available from: http://www.orientjchem.org/?p=41421