Study of Co(Aaopd) and Cu(Aaopd) Schiff-Base Catalysts Effect in Oxidation Oximes and Carboxylic Acids Derivatives

Reza Soleymani¹*, Milad Taheri², Mehdi Daryani³ and Marziye Hoseynalibeygi²

¹Young Researchers Club, Shahre-rey Branch, Islamic Azad University, Tehran, (Iran). ²Department of Chemistry, Shahre-rey Branch, Islamic Azad University, Tehran, (Iran). ³Department of Chemistry, Damghan University, Damghan, (Iran).

ABSTRACT:

Oximes and carboxylic acids derivatives have a wide range in medical, pharmaceutical, agriculture industrials. Thus they have significant effects on these fields. Base-promoted or (-RC=N-) groups of cobalt and nickel groups. These were examined for oxidative process of oximes and carboxylic acids. This process is absolutely selective and in this procedure oximes transforms to aldehyde and ketone derivatives with high yield, without more oxidative process on Aldehyde group. In this mechanism high amounts of various oximes transforms into carbonyl group. However, obtained results showed that oxidative process for oximes and carboxylic acid with presence of Base-Promoted such as Co(AAOPD) and Cu(AAOPD) because of higher speed and yield. For more evaluation of reaction progress and identification of products through different methods like were used: Thin Layer Chromatography (TLC), Gas Chromatography, FT-IR, UV-Vis and elemental analysis.

KEYWORDS:

Carboxylic acids; Carboxylic acids; Oximes; Schiff-Base

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Copy the following to cite this article: Soleymani R,Taheri M, Daryani M, Hoseynalibeygi M. Study of Co(Aaopd) and Cu(Aaopd) Schiff-Base Catalysts Effect in Oxidation Oximes and Carboxylic Acids Derivatives. Orient J Chem 2012;28(2).

Copy the following to cite this URL: Soleymani R,Taheri M, Daryani M, Hoseynalibeygi M. Study of Co(Aaopd) and Cu(Aaopd) Schiff-Base Catalysts Effect in Oxidation Oximes and Carboxylic Acids Derivatives. Available from: http://www.orientjchem.org/?p=23444