Synthesis and Characterization of some CIS [Ru(NO)XL2(PPh3)2 (X=Monodentate) Type Complexes of Nitrosylrutheitum (II)

T. Singh¹ and K.K. Singh²

¹Department of Chemistry S.G.R. Post Graduate College, Dobhi, Jaunpur - 222 149 (India).

²Department of Chemistry, T.D. Post Graduate College, Jaunpur (India).

ABSTRACT:

Nitrosyl complexes which have both L= methyl cyanide and triphenylphosphine as coexisting ligands were synthesized and characterised as cis [Ru(NO)(X)L2(PPh3)2]+2 X= OH,Cl,NO2 and L=CH3CN). The structures of the complexes have been proposed on the basis of analytical, magnetic and spectroscopic (IR, UV-Visible and 1H NMR) methods. The properties of these complexes were investigated under the conditions of chemical oxidation and electrochemical reduction.

KEYWORDS:

Nitrosylrutheitum (II); Spectroscopic methods; Chemical oxidation

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Copy the following to cite this article: Singh T, Singh K. K. Synthesis and Characterization of some CIS [Ru(NO)XL2(PPh3)2 (X=Monodentate) Type Complexes of Nitrosylrutheitum (II). Orient J Chem 2011;27(1).

Copy the following to cite this URL: Singh T, Singh K. K. Synthesis and Characterization of some CIS [Ru(NO)XL2(PPh3)2 (X=Monodentate) Type Complexes of Nitrosylrutheitum (II). Orient J Chem 2011;27(1). Available from: http://www.orientjchem.org/?p=24791