Synthesis and Characterization of the adducts of Bis(O-ethyldithiocarbonato)nickel(II) with substituted pyridines

Renu Sachar and Sanjay Kapoor

Department of Chemistry, University of Jammu, Ambedkar Road, Jammu - 180 006 (India).

ABSTRACT:

A series of adducts of Bis(O-ethyldithiocarbonato)nickel(II) with substituted pyridines have been synthesized by treating bis(O-ethyldithiocarbonato)nickel(II) with substituted pyridines in acetone. Analytical results show that the adducts have 1:1 and 1:2 stoichiometry with general formula M(Xan)2 L and M(Xan)2 L2 (M = Ni, Xan = O-ethyldithiocarbonate, L = 2-, 3- and 4- amino pyridines, 3- and 4- cyano pyridines). These addition complexes have been characterized by elemental analysis, conductivity measurements, magnetic susceptibility measurements, infrared and electronic spectral studies.

KEYWORDS:

Adducts; O-alkyldithiocarbonates(xanthates) and substituted pyridines

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Copy the following to cite this article: Sachar R, Kapoor S. Synthesis and Characterization of the adducts of Bis(O-ethyldithiocarbonato)nickel(II) with substituted pyridines. Orient J Chem 2009;25(4).

Copy the following to cite this URL: Sachar R, Kapoor S. Synthesis and Characterization of the adducts of Bis(O-ethyldithiocarbonato)nickel(II) with substituted pyridines. Orient J Chem 2009;25(4). Available from: http://www.orientjchem.org/?p=22997