Synthesis and characterisation of 4-morpholinyl thiocarbonic acid amide (MTA) and its Cu(I) complex

Jyotsna Pandey

State Forensic Science Laboratory, Sagar (India).

ABSTRACT:

4-Morpholinyl thiocarbonic acid amide synthesized and its Cu(i) complex was prepared. Both were characterized on the basis of elemental analysis, spectral studies, magnetic susceptibility measurement and amperometric titration. Analytical data indicate metal to ligand ratio 1:2. Infrared spectra showed the complexation through the S and N both. Magnetic measurement confirmed the diamagnetic behavior of the complex. An amperometric method for the estimation of Cu(I) with MTA further confirmed the MTA:Cu ratio 1:1. Experimental and calculated statistical data support the utility of the method for determination of Copper.

KEYWORDS:

4-morpholinyl thio carbonic acid amide; copper complex; spectral studies; amperometric titration

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Copy the following to cite this article: Pandey J. Synthesis and characterisation of 4-morpholinyl thiocarbonic acid amide (MTA) and its Cu(I) complex. Orient J Chem 2009;25(4).

Copy the following to cite this URL: Pandey J. Synthesis and characterisation of 4-morpholinyl thiocarbonic acid amide (MTA) and its Cu(I) complex. Orient J Chem 2009;25(4). Available from: http://www.orientjchem.org/?p=22807