Mechanistic and kinetic approach to the hydrolysis of tri-2,5-dichloro aniline phosphate in acidic media

M. K. Singh

Department of Chemistry,Government P.G. College, Dholpur - 328 001 (India).

ABSTRACT:

Kinetic study of Tri-2,5-dichloro aniline phosphate has been made in acid region (0.1 to 7.0 mol dm-3 HCl) at 80oC. Acid log rate profile has a rate maximum at 4.0 mol dm-3. Ionic strength data upto 3.0 m requires participation of conjugate acid species and to determine theoretical rates. Computed ionic strength data support this,since the estimated rates in the acid medium closely agree with those experimentally observed.PH,Salt, temperature.solvent, solvent-isotope,substrate concentration effects etc. have been studied.Bimolecular behaviour has been decided by the Arrhenius parameters and analysis of molecularity data. The triesters involves P-N bond fission which is strengthened by comparative kinetic data.

KEYWORDS:

Tri-2;5-dichloro aniline phosphate; kinetic approach

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Copy the following to cite this article: Singh M. K. Mechanistic and kinetic approach to the hydrolysis of tri-2,5-dichloro aniline phosphate in acidic media. Orient J Chem 2009;25(2).

Copy the following to cite this URL: Singh M. K. Mechanistic and kinetic approach to the hydrolysis of tri-2,5-dichloro aniline phosphate in acidic media. Available from: http://www.orientjchem.org/?p=11407