ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
     FacebookTwitterLinkedinMendeley

Kinetics of Ru(Iii) Catalysed Oxidation of Diacetonealcohol (Daa) by Trichloroisocyanuric Acid in Hoac-Hclo4 Medium

Volume 23, Number 3

Anil Kumar J. and Sondu S.*

Department Of Chemistry, University College of Science, Osmania University, Hyderabad - 500 007 (India)

Article Publishing History
Article Received on :
Article Accepted on :
Article Metrics
ABSTRACT:

Kinetics of Ru(III) catalysed oxidation of diacetonealcohol(DAA) by trichloroisocyanuricacid (TCICA) in HOAc-HClO4 medium has been investigated at 313K. The reaction exhibits zero order with respect to [TCICA] and fractional order with respect to [DAA] and [H+]. The rate increased with increase in percentage of acetic acid and addition of Cl- ions has no effect on rate. It is established that the reactive oxidising species are HOCl and H2OCl+. Based on the experimental observations a mechanism involving the hydride ion abstraction by Ru(III) in the rate determining step have been proposed and discussed.

KEYWORDS:

Kinetics of ru(iii) catalysed oxidation of diacetonealcohol

Download this article as: 

Copy the following to cite this article:

Anil Kumar J, Sondu S. Kinetics of Ru(Iii) Catalysed Oxidation of Diacetonealcohol (Daa) by Trichloroisocyanuric Acid in Hoac-Hclo4 Medium. Orient J Chem 2007;23(3).

Copy the following to cite this URL:

Anil Kumar J, Sondu S. Kinetics of Ru(Iii) Catalysed Oxidation of Diacetonealcohol (Daa) by Trichloroisocyanuric Acid in Hoac-Hclo4 Medium. Orient J Chem 2007;23(3). Available from: http://www.orientjchem.org/?p=20528


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.

About The Author