Sysnthesis and Structural Studies of 2-Acetylfuran-2-Furoylhydrazone Complexes of Cr(III), Fe(III), Ru(III) and Rh(III) Ions

R. N. Singh and Ramesh Singh

Department of Chemistry, S.G.R.P.G College, Dobhi, Jaupur - 222 149 (India)

Metal Complexes of 2-Acetylfuran -2-Furoylhydrazone of the type M (Haff) Cl3. H2O; [M=Cr(III) and Fe (III)] , M(Haff Cl3; [M=Cr (III) and Fe (III)] and [M(Haff)2Cl2] Cl; [M= Fe (III), Ru (III) and Rh (III)] as well as M (aff)2Cl [Fe(III), Cr(III)] have been prepared. Elemental analysis, Molar conductance, magnetic moment, electronic, ir and MB spectral studies have been used to chararterize these complexes. The different modes of chelation of the ligand and the stereochemistry of the complexes are discussed.

Complexes of 2-Acetylfuran; 2-Furylhydrazone