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Synthesis and Characterization of Some Mixed Ligand Complexes of Thorium (IV) With Anisaldehyde 4-Phenyl 3-Thiosemicarbazone and Various Anions

Volume 22, Number 2

G. Rajendran* and C. S. Amritha

Department of Chemistry, University College, Thiruvananthapuram - 695 036 (India)

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ABSTRACT:

Complexes of anisaldehyde-4-phenyl-3-thiosemicarbazone with Th(IV) have been isolated and characterized on the basis of elemental analysis, molar conductance and spectral studies. Complexes are ascertained the general formula {ThL2 xn} (X= NO3-, NCS-, CH3COO-, CH3CHOHCOO-, n=4; X=SO2-4, C2O42- n=2; and L= anisaldehyde-4-phenyl-3-thiosemicarbazone). Thermal behaviour of nitrato and oxalato complexes were examined. Ligand and few metal complexes were examined and screened for their antibacterial activities.

KEYWORDS:

Thorium (IV) complexes; Anisaldehyde-4-phenyl-3-thiosemicarbazone; antibacterial activity

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Rajendran G, Amritha C. S. Synthesis and Characterization of Some Mixed Ligand Complexes of Thorium (IV) With Anisaldehyde 4-Phenyl 3-Thiosemicarbazone and Various Anions. Orient J Chem 2006;22(2).

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Rajendran G, Amritha C. S. Synthesis and Characterization of Some Mixed Ligand Complexes of Thorium (IV) With Anisaldehyde 4-Phenyl 3-Thiosemicarbazone and Various Anions. Orient J Chem 2006;22(2). Available from: http://www.orientjchem.org/?p=19515

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