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Synthesis Spectral and Antimicrobial Studies Triphenylphosphine/Triphenylarsine Complexes Ruthenium(Ii) With Mono Basic Bidentate Thiosemicarbazones

Volume 21, Number 2

K. P. Balasubramanian and V. Chinnusamy

Department of Chemistry, Sri Ramakrishna Mission Vidyalaya Collegs of Arts and Science, Coimbatore - 641 020 (India)

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ABSTRACT:

The synthesis and characterization of several hexa-coordinated Ru(ll) Schiff base complexes of the type [RuX(CO)(EPh3)2 LL'] (E=P or As: X=H or CI:LL’ = Anion of the Schiff bases derived by the condensation of thiosemicarbazide and p-tolualdehyde or p-anisaldehyde or o-chlorobanzaldehyde are reported IR electronic and 1H NMR spectra of the complexes are discussed. An octahedral geometry has been tentatively proposed for all these complexes. The complexes also exhibited antibacterial activity against E. coli. Aeromonas hydrophilla and Salmonella typhi. The activity was compared with standard Streptomycin.

KEYWORDS:

Bidentate thiosemicarbazones; Ruthenium complexes; Anitimicrobial studies

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Balasubramanian K. P, Chinnusamy V. Synthesis Spectral and Antimicrobial Studies Triphenylphosphine/Triphenylarsine Complexes Ruthenium(Ii) With Mono Basic Bidentate Thiosemicarbazones. Orient J Chem 2005;21(2).

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Balasubramanian K. P, Chinnusamy V. Synthesis Spectral and Antimicrobial Studies Triphenylphosphine/Triphenylarsine Complexes Ruthenium(Ii) With Mono Basic Bidentate Thiosemicarbazones. Orient J Chem 2005;21(2). Available from: http://www.orientjchem.org/?p=19102

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