ISSN : 0970 - 020X, ONLINE ISSN : 2231-5039
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Micellar Catalysis of Hydroperoxide Anion Assisted Hydrolysis of Mono-2,4-Dichlorophenyl Phosphate Ester

Volume 21, Number 2

1Anupam Singh, 1Meera Sharma and 2Pratibha Singh

1Department of Chemistry, Agra College, Agra (India) 2Department of Chemistry, I.B.S., Dr. B.R.A. University, Agra (India)

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ABSTRACT:

The micellar catalysed reactions of hydroxide and hydroperoxide anions with mono-2,4-dichlorophenyl phosphate has been investigated. Borate ion accelerate the reaction. The kinetic rate data in [OH-] can be accounted for quantitatively in term of the pseudophase ion exchange model, but this model fits rate data only qualitatively for reaction of [HO2-].

KEYWORDS:

Micellar catalysis; Substituted phosphate ester

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Singh A, Sharma M, Singh P.Micellar Catalysis of Hydroperoxide Anion Assisted Hydrolysis of Mono-2,4-Dichlorophenyl Phosphate Ester. Orient J Chem 2005;21(2).

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Singh A, Sharma M, Singh P.Micellar Catalysis of Hydroperoxide Anion Assisted Hydrolysis of Mono-2,4-Dichlorophenyl Phosphate Ester. Orient J Chem 2005;21(2). Available from: http://www.orientjchem.org/?p=19073

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