Preparation of Complex by Non-Faradic Electrolytic Technique

S. R. Kshirsagar¹ and Arvlnd M. Bhlle²

¹Department of Physics, Shri Shivaji College, Parbhanl - 431 401 India.

²S.C. Railway College, Purna, Dist. Parbhanl - 431 611 India.

ABSTRACT:

Investigations reported in this paper highlights the importance of suitably modifying ionic migration and diffusion m a W-cell so as to get some useful complexes. It is well known that starting form K2Cr2O7 and Na2^- EDTA solutions, obtaining the Cr(lll)-EDTA is a laborious chemical process as healing of the solution and reduction of Chromium are pre-requisttes for complexation in this case. Taking advantage of the excess heat generated in W-cell due to non-faradic electrolytic process, both varieties of Cr(III)-EDTA complex, separated by a neutral zone have been obtained by mixing Na2-EDTA and K2Cr2O7 in different proportions and carrying out the electrolysis at a constant Dc voltage in W-cell.

KEYWORDS:

modifying; pre-requisttes; complexation EDTA

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Copy the following to cite this article: Kshirsagar S. R, Bhlle A. M. Preparation of Complex by Non-Faradic Electrolytic Technique. Orient J Chem 2000;16(2).

Copy the following to cite this URL: Kshirsagar S. R, Bhlle A. M. Preparation of Complex by Non-Faradic Electrolytic Technique. Orient J Chem 2000;16(2). Available from: http://www.orientjchem.org/?p=36335