Synthesis and Characterization of Dioxouranium (Vi) Complexes of Schiff Base Ligands

Kishor Aroraa¹, R. C. Goyabb² and D. D. Agarwalc³

¹Department of Chemistry, Government Auto. K.R.G. College, Gwalior - 474 002 India.

²Department of Chemistry, Government Post Graduate College, Morena - 476 001 India.

³School of Studies in Chemistry, Jiwaji University, Gwalior - 474 011 India.

ABSTRACT:

A series of 12 new complexes of dioxouranium (VI) with two schiff base ligands viz 2 N-(3-methoxy-4-hydroxy benzaiidene) amino pyridine (MHBAPy) and 2N-(Salicylidene) aminopyrkfine (SAPy) were prepared in non aqueous media having the general composition UO2X2.2L(X=N03, Br, I, NCS and CH3COO) or U02 (CIO4)24L (L=MHBAP or SAPy) and characterized on the basis of elemental analyses, electrical conductance, IR and electronic spectral studies. The X-ray diffraction studies of one of the complex has been done successfully and reported. The probable coordination number of these complexes has tentatively been assigned as 6 or 8 depending upon the nature of anions.

KEYWORDS:

Dioxouranium complexes; Configuration; X-ray analysis; Synthesis.

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Copy the following to cite this article: Aroraa K, Goyabb R. C, Agarwalc D. D. Synthesis and Characterization of Dioxouranium (Vi) Complexes of Schiff Base Ligands. Orient J Chem 2000;16(1).

Copy the following to cite this URL: Aroraa K, Goyabb R. C, Agarwalc D. D. Synthesis and Characterization of Dioxouranium (Vi) Complexes of Schiff Base Ligands. Orient J Chem 2000;16(1). Available from:http://www.orientjchem.org/?p=36718