Ruthenium (III) Catalysed Kinetic Study of Oxidative Decarboxylation of n-Butyric Acid and Iso-Butyric Acid by Ceric Sulphate in A Aqueous Sulphuric Acid Medium

Y. Rajeshwer Rao and M. Kodandarami Reddy

Department of Chemistry, A.V. College, Gagan Mahal, Domalguda, Hyderabad, India.

ABSTRACT:

Ruthenium In trace amount (10-6 mol dm3) was found to catalyse the oxidative decarboxylation of n-butyric acid and iso-butyricacid by eerie sulphate. A mechanism involving Ru (III) - substrate complex was proposed. Rate constant (k), formation constant (K) and the relevant thermodynamic parameters were evaluated and discussed.

KEYWORDS:

oxidative decarboxylation; iso-butyricacid; thermodynamic

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Copy the following to cite this article: Rao Y. R, Reddy M. K. Ruthenium (III) Catalysed Kinetic Study of Oxidative Decarboxylation of n-Butyric Acid and Iso-Butyric Acid by Ceric Sulphate in A Aqueous Sulphuric Acid Medium. Orient J Chem 1998;14(1).

Copy the following to cite this URL: Rao Y. R, Reddy M. K. Ruthenium (III) Catalysed Kinetic Study of Oxidative Decarboxylation of n-Butyric Acid and Iso-Butyric Acid by Ceric Sulphate in A Aqueous Sulphuric Acid Medium. Orient J Chem 1998;14(1). Available from: http://www.orientjchem.org/?p=21624