Synthesis of Some New 1-[Substituted 1, 4-Benzoxazin-3 (2h)-Onyl-1-Oxo/1-Oxo-Methyl/1-Methyl-Oxo-i-3-Methyl, Pyrazol-5-Ones

M. B. Hogale And B. N. Pawar

Department of Chemistry, Shivaji University, Kolhapur-416 004 India.

ABSTRACT:

Synthesis of 1-[Substituted 1, 4-azin-benzox-3-(2H)-onyl-1-oxo-]-3-methyl pyrazoI-5-ones IIa1-7 1 -[substituted 1, 4-benzoxazin-3 (2H) onyl-1-oxo-methyl]-3-methyl, pyrazol-5-ones IIb1-5 and 1-{substituted 1. 4-benzoxazrn~3 (2HV-onyl-methyl-oxo-] IIc1-3 have been reported. 4-hydrazido/4-hydrazinoacetyl/4-hydrazkfoacetyl, 4-benzoxazin-3 (2H)-ones were condensed with ethylaceto acetate in dioxane followed by cyclisation in refluxing O-dichlorobenzene to give targetted pyrazoles IIa, b, c. The structures of these compounds were confirmed by IR,NMRand elemental analysis.

KEYWORDS:

Synthesis; 4-Benzoxazin

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Copy the following to cite this article: Hogale M. B, Pawar B. N. Synthesis of Some New 1-[Substituted 1, 4-Benzoxazin-3 (2h)-Onyl-1-Oxo/1-Oxo-Methyl/1-Methyl-Oxo-i-3-Methyl, Pyrazol-5-Ones. Orient J Chem 1989;5(2).

Copy the following to cite this URL: Hogale M. B, Pawar B. N. Synthesis of Some New 1-[Substituted 1, 4-Benzoxazin-3 (2h)-Onyl-1-Oxo/1-Oxo-Methyl/1-Methyl-Oxo-i-3-Methyl, Pyrazol-5-Ones. Orient J Chem 1989;5(2). Available from: http://www.orientjchem.org/?p=41403