Synthesis and Characterization of A,A'-Bis(Isothiouronium)-Ortho-Xylene and N,N'-Bis (Ortho-Carbonylbenzoic Acid)- A,A'-Diamino-Ortho-Xylene

D. Azarifar and A. Niakanipour

Department of Chemistry, Bu-Ali Sina University, Hamadan Iran.

ABSTRACT:

Ben zylic and pseudo-benzylic positions provide a convenient site in nucleophilic substitution reactions, which is attributed to involvement of some stable carbocationic-type reaction intermediates, it is observed that thiourea and potassium phthalimide can readily attach both a and a' positions in a,a>-dibromc-oi1ho-xylene to produce a,a'*bis (isothiouranium)-ortho-xylene and a,a'-bis(phthalimide)-ortho-xylene respectively as supported by their IR, 1H nmr, 13C nmr, Mass spectra and micro analysis.

KEYWORDS:

pseudo-benzylic; Nucleophilic; phthalimide; 1H nmr

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Copy the following to cite this article: Azarifar D, Niakanipour A. Synthesis and Characterization of A,A'-Bis(Isothiouronium)-Ortho-Xylene and N,N'-Bis (Ortho-Carbonylbenzoic Acid)-A,A'-Diamino-Ortho-Xylene. Orient J Chem 2000;16(1).

Copy the following to cite this URL: Azarifar D, Niakanipour A. Synthesis and Characterization of A,A'-Bis(Isothiouronium)-Ortho-Xylene and N,N'-Bis (Ortho-Carbonylbenzoic Acid)-A,A'-Diamino-Ortho-Xylene. Orient J Chem 2000;16(1). Available from:http://www.orientjchem.org/?p=36714