Synthesis, Mechanistic Interpretation and Kinetic Study of 2,6 Di-methylphenyl Phosphate Monoester in Acid Medium
Shweta Chand*, Praveen Kumar, Nandlal and Ruchi Singh
Department of Chemistry, Christ Church College, Kanpur (India).
Extensive kinetic study has been carried out on the hydrolysis of mono-2,6-dimethylphenyl phosphate ester in acid 0.1 to 6.0 mol. dm-3.HCl and buffers from 1.24 to 7.46 pH at 97± 0.5°C in water. Systematic ionic data proves the presence of acid catalyzed hydrolysis. The monoester has been found to be hydrolysis by conjugate acid, mono-negative, neutral and di -negative species. The inorganic phosphate obtained in overall hydrolysis has been estimated by Allen
KEYWORDS:Mechanistic Interpretation; Kinetic study; Acid medium
Download this article as:Copy the following to cite this article: Chand S, Kumar P, Nandlal N, Singh R. Synthesis, Mechanistic Interpretation and Kinetic Study of 2,6 Di-methylphenyl Phosphate Monoester in Acid Medium. Orient J Chem 2011;27(3). |
Copy the following to cite this URL: Chand S, Kumar P, Nandlal N, Singh R. Synthesis, Mechanistic Interpretation and Kinetic Study of 2,6 Di-methylphenyl Phosphate Monoester in Acid Medium. Orient J Chem 2011;27(3). Available from: http://www.orientjchem.org/?p=24546 |
This work is licensed under a Creative Commons Attribution 4.0 International License.