Effect of Dielectric Constants of Methanol- Water and Acetone-Water Mixtures on Proton-Ligand and Metal-Ligand Stability Constants of Cu(II)-Salicylic Acid Complex
K. T. Kirnapure1, P. J. SOndawale2 and B. D. Saraf3
1Mahatma Gandhi Junior College, Armori, Distt. Gadchiroli - 441 208 (India).
2Department of Chemistry, Government Polytechnic, Sardar Nagpur (India).
3Department of Chemistry, Institute of Science, Nagpur (India).
The interaction between Cu(II) and salicylic acid has shown 1:1 and 1:2 complex formation. The complex formation has been investigated pH metrically in different percentage of methanol-water and acetone-water mixture at temperature (29oC + 0.1oC). The method Bjerrem and Kelvin as modified by Irving and rossotti has been used in the present work. It shows that proton – ligand and metal – ligand stability constant increased with increasing the percentages of methanol – water and acetone – water.
KEYWORDS:Dielectric constants; protons ligand; stability constants
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| Copy the following to cite this article: Kirnapure K. T, SOndawale P. J, Saraf B. D. Effect of Dielectric Constants of Methanol- Water and Acetone-Water Mixtures on Proton-Ligand and Metal-Ligand Stability Constants of Cu(II)-Salicylic Acid Complex. Orient J Chem 2010;26(2). |
| Copy the following to cite this URL: Kirnapure K. T, SOndawale P. J, Saraf B. D. Effect of Dielectric Constants of Methanol- Water and Acetone-Water Mixtures on Proton-Ligand and Metal-Ligand Stability Constants of Cu(II)-Salicylic Acid Complex. Orient J Chem 2010;26(2). Available from: http://www.orientjchem.org/?p=24073 |
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