Synthesis of 1,5-Disubstituted 2,4 Dithiobiurets and Studies on their Complexation Behviour

Mohsin Hasan Khan, N. K. Agarwal and Shamim Ahmad

Department of Chemistry,Bareilly College, Bareilly - 243 005 (India).

ABSTRACT:

1,5-Disubstituted 2,4-dithiobiuret selected for the present studies were, 1,5 di-o-tolyl 2,4-dithiobiuret (DOTDTB),1,5-di-p-phenetyl 2,4-dithiobiuret(DPhDTB),1,5-dimethyl 2,4 dithiobiuret(DMDTB). The ligands were synthesized by the standard method and characterized by TLC, elemental analyses I.R.spectra and melting-points. The complexes of these ligands with the metals Co, Ni & Cu were prepared and characterized by elemental analyses, melting-points,magnetic moments, molar conductance I.R. spectra & Potentiometric studies. Tetrahedral structure have been proposed for these complexes.

KEYWORDS:

Tetrahedral 2,4 dithiobiurets

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Copy the following to cite this article: Khan M. H, Agarwal N. K, Ahmad S. Synthesis of 1,5-Disubstituted 2,4 Dithiobiurets and Studies on their Complexation Behviour. Orient J Chem 2009;25(3).

Copy the following to cite this URL: Khan M. H, Agarwal N. K, Ahmad S. Synthesis of 1,5-Disubstituted 2,4 Dithiobiurets and Studies on their Complexation Behviour. Orient J Chem 2009;25(3). Available from: http://www.orientjchem.org/?p=23107