Coordination Behaviour of Tungsten (VI) Towards Triazene-1-Oxide

Ramadhar Sharma¹ and S. N. Sharma²

¹R. D. and D. J. College, Munger - 811 201 India.

²K.S. S. College, Lakhisarai - 811 311 India.

ABSTRACT:

The coordination compounds of tungsten (VI) were obtained using monochloro penta (Phenoxo) tungsten (VI). The ligands used were variedly substituted monobasic bidentate / tri-dentate triazene- 1-oxides. The stoichtometry of complexes and stereochemistry has been arrived using, elemental analyses, conductance measurements in nitromethane, molecular complexities in freezing benzene and I.R. spectra. Seven coordinate pentagonal bipyramidal structure has been assigned to these complexes.

KEYWORDS:

tri-dentate; stereochemistry; monobasic nitromethane

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Copy the following to cite this article: Sharma R, Sharma S. N. Coordination Behaviour of Tungsten (VI) Towards Triazene-1-Oxide. Orient J Chem 1998;14(1).

Copy the following to cite this URL: Sharma R, Sharma S. N. Coordination Behaviour of Tungsten (VI) Towards Triazene-1-Oxide. Orient J Chem 1998;14(1). Available from: http://www.orientjchem.org/?p=21680