Potentiometric Determination of Mercury Ions by Ion Imprinted Polymer Coated Multiwall Carbon Nanotube: High Selective Sensor for Determination of Trace Amounts of Mercury Ions in Biological Samples

Mohammad Karimi, Forouzan Aboufazeli, Hamid Reza Lotfi Zadeh Zhad, Omid Sadeghi and Ezzatollah Najafi*

Department of Chemistry, Shahr-e-Rey Branch, Islamic Azad University, P. O. Box 18735-334, Tehran, Iran.

ABSTRACT:

A Hg(II) ion imprinted polymer was synthesized and coated on multiwall carbon nanotube. This material was used for modification of a carbon paste electrode. The electrode was used for determination of trace amounts of mercury (II) ions in aqueous media. The electrode composition was graphite powder 66%, paraffin 24% and IIP@MWCNTs 11% (W/W). The linear range for mercury (II) was 8.0×10-8 to 3.5×10-3 mol L”1 and the limit of detection was obtained6.3×10"8 mol L”1. The response time and lifetime of the electrode were improved by coating of IIP on MWCNTs surface. The Method validation was performed by analyzing of some standard reference materials.

KEYWORDS:

Carbon paste electrode; Mercury; Modified MWCNTs; Potentiometry; Ion imprinted polymer

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Copy the following to cite this article: Karimi M, Aboufazeli F, Zhad H. R. L. Z, Sadeghi O, Najafi E. Potentiometric Determination of Mercury Ions by Ion Imprinted Polymer Coated Multiwall Carbon Nanotube: High Selective Sensor for Determination of Trace Amounts of Mercury Ions in Biological Samples. Orient J Chem 2012;28(4).

Copy the following to cite this URL: Karimi M, Aboufazeli F, Zhad H. R. L. Z, Sadeghi O, Najafi E. Potentiometric Determination of Mercury Ions by Ion Imprinted Polymer Coated Multiwall Carbon Nanotube: High Selective Sensor for Determination of Trace Amounts of Mercury Ions in Biological Samples. Available from: http://www.orientjchem.org/?p=11896